Acron Paints

Acron Paints, Unit 6 William Street, Northam, Southampton, Hants. S014 5QH
Tel: 023 80 223266 Fax: 08700 527587

Material Safety Data SheetRevision No.3/2002
 
Suppliers Name and Address:
Acron Paints
Unit 6, William Street, Northam
Southampton, Hants. S014 5QH
Tel: 023 80 223266 Fax: 08700 527587
Product Name/s:
Acetone
  1. Identification of Substance

    Acetone.

  2. Compostion/information on Ingredients

    Ingredient NameEINECS No.Cas NoContentsHealth
    (Class)
    Risk (R No)
    Acetone200-662-267-64-1100%F, Xi11,36,66,67

  3. Hazards Identification

  4. First Aid Measures

    General

    Keep affected person away from heat, sparks and flames.

    Inhalation

    Remove victim immediately from source of exposure. Move the exposed person to fresh air at once. Perform artificial respiration if breathing has stopped. When breathing is difficult, properly trained personnel may assist by administering 100% oxygen. Keep the affected person warm and at rest. Seek prompt medical attention.

    Ingestion

    Rince mouth thoroughly. Do not induce vomiting. Never make an unconscious person vomit or drink fluids. Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Seek medical attention immediately. If there is difficulty breathing, give oxygen. If breathing stops or shows signs of failing, apply artificial respiration.

    Skin

    Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with plenty of water. Seek medical attention promptly if symptoms occur after washing. Continue washing skin or at least 20 minutes. Obtain medical attention if blistering occurs or redness persists.

    Eyes

    Promptly wash eyes with plenty of water while lifting the eyes .Make sure to remove any contact lenses from eyes prior to rinsing. Continue for at least 20 minutes. Get medical attention urgently.

  5. Fire Fighting Measures

    Extinguishing Media

    Do not use water jet.

    Special Fire Fighting Procedures

    Keep run-off water out of sewers and water sources. Dike for water control. Avoid water in straight hose stream, will scatter and spread fire. Use water spray to reduce vapours. If risk of water pollution occurs, notify appropriate authorities. Water may be ineffective but use to keep fire-exposed containers cool. In case of fire, wear self contained breathing apparatus.

    Unusual Fire and Explosion Hazards

    Extremely flammable. May explode in a fire.

    Hazardous Decomposition Products

    Fire creates: Oxides of: Carbon.

    Protective Measures in Fire

    Wear suitable respiratory protection when dealing with a fire.

  6. Accidental Release Measures

    Personal Precautions During Spill

    Wear appropriate protective clothing and respiratory protection. Acoid breathing vapour. Ensure good ventilation. Repeated exposure can cause skin dryness and cracking. Vapour may cause drowsiness and dizziness.

    Precautions to Protect Environment

    Do not let the product or washing down water enter natural water courses or the sewers.

    Spill Cleanup Methods

    Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Provide ventillation and confine spill. Do not allow runoff to sewer. Absorb in vermiculite, dry sand or earth and place into containers.

  7. Handling and Storage

    Usage Precautions

    Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. Keep away from heat, sparks and open flame. Keep container tightly closed when not in use.

    Storage Precautions

    Flammable/combustible - Keep away from oxidizers, heat and flames. May attack some plastics, rubber and coatings. Keep in cool, dry, ventilated storage and closed containers. Ground container and transfer equipment to eliminate static electric sparks.

    Storage Criteria

    Flammable liquid storage. Suitable storage materials are: mild steel, stainless steel, aluminium and its alloys, copper and its alloys. Do not store in certain plastics.

  8. Ingredient Name

    Ingredient NameCas No.STDLT Exp
    (8 hours)
    ST Exp
    (15 mins)
    Acetone67-64-1OES500 ppm (sk)1500 ppm (sk)

    Protective Equipment

    Use approved safety goggles or face shield. Use long-sleeved protective gloves made from butyl rubber.

    Ventilation

    Provide adequate general and local exhaust ventilation.

    Protective Gloves

    Use protective gloves made of Butyl rubber. Use gloves with long sleeves. Ensure gloves are manufactured/tested in accordance with BS EN 374. Determined penetration times carried out in accordance with EN374 part III ar enot performed under practical conditions. Therefore a maximum wearing time corresponding to 50% of the penetration time is recommended.

    Eye Protection

    If risk of splashing, wear safety goggles or face shield. Ensure safety glasses conform to EN166.

    Other Protection

    Use engineering controls to reduce air contamination to permissible exposure level. Provide eyewash station and safety shower. Wear apprpriate clothing to prevent repeated or prolonged skin contact. Wear air-supplied mask in confined areas. Use respiratory protection if there is a risk of high vapour concentrations.

    Hygienic Work Routines

    Wash at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet or contaminated. Do not smoke in work area. Isolate contaminated clothing and wash before reuse.

  9. Physical and Chemical Properties

    AppearanceClear LiquidColourColourless
    Odour / TastePungentFlash Point-18°C
    Solubillity TextSoluble in waterFlash Point MethodOpen Cup
    Solubility Value100g/100g of H2O at 20°CMelting Point-95°C
    Vapour Pressure24.70kPa at 20°CBoiling Point~56°C
    Auto Ignition Temperature465°CEvaporation Rate9.46
    Specific Gravity0.79 at 20°CUpper Flammability Limit13%
    Partition Coeff. (Water/Octanol)-0.24Lower Flammability Limit2.6%

  10. Stability and Reactivity

    Stability

    Normally stable. Avoid heat, sparks, flames, air and oxidizers, hygroscopic.

    Conditions to avoid

    Avoid heat, flames and other sources of ignition. Avoid contact with oxidisers. Avoid exposure to water or moisture.

    Hazardous Decomposition Products

    Fire creates: Oxides of: Carbon.

  11. Toxicological Information

    Low order of acute toxicity. A single application to the rabbit eye produced conjunctival irritation and transient corneal damage (stippling epithelial damage). A single 4h semi-occlusive to intact rabbit skin produced no sign of dermal irritation. The product did not exhibit mutagenic activity (with and without metabolic activation) in : Salmonella typhimurium. Chinese hamster cells and human lymphocytes. Negative results were achieved during studies designed to investigate the potential to induce birth defects by inhalation.

    Toxic Dose1-LD50

    1700-10700mg/kg (oral rat).

    Toxic Conc.-LD50

    >6700.00mg/l/4h (inh-rat).

    Inhalation

    Vapours may cause drowsiness and dizziness.

    Skin

    Repeated exposure can cause skin dryness and cracking.

    Health Warnings

    Gas or vapour is harmful on prolonged exposure or in high concentration. Irritant of eyes and mucous membranes. Narcotic effect. CND depressant. Prolonged or repeated contact leads to drying of skin. Conjunctivitis and lacrimation. Mild dermatitis, allergic skinrash.

    Target Organs

    Central nervous system. Eyes. Gastro-intestinal tract. Respiratory system, lungs. Skin.

    Medical Symptoms

    Irritation of eyes and mucous membranes. Upper respiratory irritation. Skin irritation. Nausea, vomiting. Central nervous system depression. Drowsiness, dizziness, disorientation, vertigo. Mild intoxication (incl. fatigue, lassitude, irratability, headache, nausea).

    Medical Considerations

    Skin disorders and allergies.

  12. Ecological Information

    Environmental Hazards

    There is evidence that it is degraded under anaerobic conditions. Considered by the UN ad episodic ozone. The product will dissolve rapidly in water but is poorly absorbed onto soils or sediments. This product is volatile/gaseous and will partition to the air phase, siddolve rapidly in water and is poorly absorbed onto soils or sediment.

    Degradability

    Product is not expected to bioaccumulate. Bioconcentration factor = .69 for haddock. The product is readily biodegradeable in aerobic systemd using either salt water of resh-water innocula. BOD5 = 38-56% of ThOD., BOD20 = 76-84% of ThOD.

    Acute Fish Toxicity

    This product is rated as non-hazardous to aquatic species. LC50 96h > 5500mg/litre. EC50 24h daphnia > 10000 mg/litre. Toxicity threshold conentration. 7500 mg/litre algae. Product should not adversely affect biological treatment facilities.

  13. Disposal Considerations

    General/Cleaning

    Contaminated packages must be completely emptied before sending away for laundering and re-use.

    Disposal Methods

    Incinerate in suitable combustion chamber. Absorb in vemiculite or dry sand, dispose in licensed special waste. Confirm disposal procedures with environmental engineer and local regulations. Do not allow runoff to sewer, waterway or ground. Contaminated packs should be emptied as far as possible, they can then be passed on for recycling after being thoroughly cleaned. Do not incinerate closed containers. Do not cut, puncture or weld on or near to the container. These goods and packaging must be disposed of in accordance with the Special Waste Regulations 1996.

    EWC Number

    Allocation of a waste code number in accordance with the European Waste catalogue, shohuld be carried out in agreement with an EA authorised waste disposal company.

  14. Transport Information

    Label for Conveyance

    Flammable Liquid.

    Road
    UN Number1090Hazard Class (ADR)Class 3ADR Class Number3
    ADR Pack GRIIADR Label Number3Hazchem Code2YE
    CEFIC TEC(R) Number30Proper Shipping Name2-Propanone
    Rail
    Rail Transport Class3RID Pack GRII
    Sea
    UN Sea1090Sea Transport Class3IMDG Page3102
    Sea Pack GRIIMarine PollutantNo
    Air
    UN Air1090Air Transport Class3Air Pack GRII

  15. Regulatory Information

    EEC (EINECS) Number

    200-662-2

    Label for supply

    Highly flammable & Irritant.

    Risk Phrases

    Safety Phrases

  16. Other Information

    User Notes

    Since emptied containers retain product residue, follow label warnings even after container is emptied. Residual vapours may explode on ignition. Do not cut, drill, grind or weld on or near this container. Labels should not be removed from containers until they have been cleaned and no product remains within. This health and safety Data Sheet has been issued in accordance with the Chemicals (Hazards and Packaging for Supply) Regulations 1999.

  17. R Phrases

The information contained in this safety data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging) Regulations. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written instructions. As the specific conditions of use of the product are outside of the suppliers control, the user is responsible for ensuring that the requirements of relevant legislation are complied with.

Acron Paints March 2005Acetone

Acron Health and Safety

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